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Chemistry

Saponification Value Calculator

Calculate the saponification value of a fat or oil from a back-titration against potassium hydroxide.

Your inputs

Change any value to update the result instantly.

Chemistry
mL
mL
eq/L
g

Saponification value

154.275 mg KOH/g

Titre difference

11 mL

KOH consumed by the sample

5.5 meq

Equivalent NaOH value

110 mg NaOH/g

Average molar mass of the fatty acids

1,090.9 g/mol (triglyceride)

The factor 56.1 is the molar mass of KOH in g/mol, which converts milliequivalents into milligrams of KOH.

What this calculator does

Calculates the saponification value of a fat or oil from a back-titration of excess potassium hydroxide.

What your result means

Milligrams of KOH needed to saponify one gram of the oil. A higher value means shorter average fatty-acid chains.

Formula and working

SV = (V_blank − V_sample) × N_KOH × 56.1 ÷ m_sample

  1. 1

    Collect the inputs

    Titre for the blank (V_blank) = 26 mL; Titre for the sample (V_sample) = 15 mL; Normality of the acid used (N) = 0.5 eq/L; Mass of the oil sample (m) = 2 g

  2. 2

    Apply the formula

    SV = (V_blank − V_sample) × N_KOH × 56.1 ÷ m_sample

  3. 3

    Result

    Saponification value = 154.275 mg KOH/g

Frequently asked questions

Symbols and assumptions

SV
Saponification value in mg KOH per g
V_blank, V_sample
Titre volumes in mL
N
Normality of the titrant
m
Sample mass in g
  • The blank and sample are titrated with the same standard acid.
  • The factor 56.1 is the molar mass of KOH in g/mol.

Sources and review

Reviewed 2026-09-22 · Next review 2027-09-22

  • Free fatty acids and unsaponifiable matter shift the result; the triglyceride molar mass shown is an approximation.

Important limitation

This is an educational estimate based only on the values and formula shown. Verify current rates, rules, units, and professional standards before relying on the result. It is not personalized financial or investment advice.

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